含铅汽油在被发明的那一天起就是公认的毒药(2016)
Leaded gas was a known poison the day it was invented (2016)

原始链接: https://www.smithsonianmag.com/smart-news/leaded-gas-poison-invented-180961368/

1921年,通用汽车工程师托马斯·米基利(Thomas Midgley Jr.)发现四乙基铅(TEL)能有效防止发动机“爆震”。尽管通用汽车和石油公司明知四乙基铅是剧毒物质,但为了获得专利控制权并从中牟利,仍将其作为首选添加剂,而非采用乙醇等更安全的替代品。 尽管早期炼油厂工人的死亡报告引发了警告,但公共卫生官员却对普通民众面临的风险不予理会,并以“留给下一代”去解决为由,搪塞了关于长期环境累积风险的担忧。含铅汽油在随后的几十年里成为行业标准,导致全球范围内的空气和土壤遭受污染。 这造成了毁灭性的环境与人类代价。研究显示,长期接触铅会导致儿童神经受损、发育迟缓及行为问题;甚至有证据表明,接触铅与暴力犯罪率上升存在相关性。直到20世纪70年代中期,美国国家环境保护局(EPA)才开始通过漫长的法律斗争,逐步淘汰含铅汽油。如今,我们仍在承受这一决策的遗毒,因为20世纪中叶排放的铅残留在环境中,即便其使用早已停止,却依然持续危害着公众健康。

这篇 Hacker News 的讨论围绕着《史密森尼杂志》2016 年的一篇文章展开,该文章指出含铅汽油的毒性在其诞生之初就已为人所知。 评论者们讨论了托马斯·米基利(Thomas Midgley Jr.)令人诟病的遗产,作为含铅汽油和氟氯烃的发明者,他自身的健康状况也常被提及,充满讽刺意味。虽然一些参与者幽默地将现代社会的种种问题归咎于长期接触铅的影响,但另一些人则对其持续使用表示了严重关切。具体而言,该帖强调,尽管科学界已达成共识,确认铅会造成不可逆的损害,但它在全球范围内的螺旋桨飞机航空燃油中仍被广泛使用。
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原文
Standard_Stations_filling_station_in_California_1939.jpg
A Standard Stations filling station in California, circa 1939. Wikimedia Commons

For most of the mid-twentieth century, lead gasoline was considered normal. It wasn’t: lead is a poison, and burning it had dire consequences. But how did it get into gasoline in the first place?

The answer goes back to this day in 1921, when General Motors engineer named Thomas Midgley Jr. told his boss Charles Kettering that he’d discovered a new additive which worked to reduce the “knocking” in car engines. That additive: tetraethyl lead, also called TEL or lead tetraethyl, a highly toxic compound that was discovered in 1854. His discovery continues to have impact that reaches far beyond car owners.

Kettering himself had designed the self-starter a decade before, wrote James Lincoln Kitman for The Nation in 2000, and the knocking was a problem he couldn’t wait to solve. It made cars less efficient and more intimidating to consumers because of the loud noise. But there were other effective anti-knock agents. Kitman writes that Midgley himself said he tried any substance he could find in the search for an antiknock, “from melted butter and camphor to ethyl acetate and aluminum chloride.” The most compelling option was actually ethanol.

But from the perspective of GM, Kitman wrote, ethanol wasn’t an option. It couldn’t be patented and GM couldn’t control its production. And oil companies like Du Pont "hated it," he wrote, perceiving it to be a threat to their control of the internal combustion engine.

TEL filled the same technical function as ethanol, he wrote: it reduced knock by raising the fuel's combustability, what would come to be known as "octane." Unlike ethanol, though, it couldn't be potentially used as a replacement for gasoline, as it had been in some early cars. The drawback: it was a known poison, described in 1922 by a Du Pont executive as "a colorless liquid of sweetish odor, very poisonous if absorbed through the skin, resulting in lead poisoning almost immediately." That statement is important, Kitman wrote: later, major players would deny they knew TEL to be so poisonous.

So in February 1923, a filling station sold the first tank of leaded gasoline. Midgley wasn’t there: he was in bed with severe lead poisoning, writes History.com. The next year, there was serious backlash against leaded gasoline after five workers died from TEL exposure at the Standard Oil Refinery in New Jersey, writes Deborah Blum for Wired, but still, the gasoline went into general sale later that decade. In 1926, she writes, a public health service report concluded there was “no reason to prohibit the sale of leaded gasoline” so long as workers were protected when they made it. Blum continues:

The task force did look briefly at risks associated with every day exposure by drivers, automobile attendants, gas station operators, and found that it was minimal. The researchers had indeed found lead residues in dusty corners of garages. In addition,  all the drivers tested showed trace amounts of lead in their blood. But a low level of lead could be tolerated, the scientists announced.

That report acknowledged that exposure levels might rise over time. “But, of course, that would be another generation’s problem,” she writes. Those early actions set a precedent that was hard to undo: it wouldn’t be until the mid-1970s that a growing body of evidence about the dangers of leaded gasoline lead the EPA to enter into a years-long legal struggle with gasoline-makers over phasing out leaded gasoline.

The effects of so much lead being burned and forced into the air are still being felt in the United States and other countries where leaded gasoline was—or still is—used.

“Chidren are the first and worst victims of leaded gas; because of their immaturity, they are most susceptible to systemic and neurological injury,” wrote Kitman. Research has shown that lead exposure in children is linked to "a whole raft of complications later in life," writes Kevin Drum for Mother Jones, among them lower IQ, hyperactivity, behavioral problems and learning disabilities. A significant body of research links lead exposure in children to violent crime, he writes. Much of that lead is still around in environments that were contaminated by gasoline fumes during the era of unleaded. It's a problem that can't be left for another generation, Drum writes.

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