巴拉洛依德B-72
Paraloid B-72

原始链接: https://en.wikipedia.org/wiki/Paraloid_B-72

Paraloid B-72 是一种耐用、不易发黄的丙烯酸树脂,最初为涂料和油墨开发,现广泛用作保护和修复中的粘合剂。从化学成分上看,它是一种甲基丙烯酸乙酯-甲基丙烯酸酯共聚物,可溶于丙酮和乙醇等溶剂。 它的受欢迎源于其强度和柔韧性优于常用的聚醋酸乙烯酯等替代品,为修复提供良好的应力耐受性。它被用于稳定陶瓷、玻璃、化石,甚至硬化钢琴琴槌,以及用于博物馆标签。 虽然应用可能比较困难,但通过调整溶剂混合物(通常使用丙酮、乙醇和甲苯)可以使保护人员控制工作时间和最终树脂性能。与某些树脂不同,B-72 不需要增塑剂来保持稳定性,添加气相二氧化硅可以改善加工性能并在固化过程中改善应力分布。最近,它甚至被用于为损坏的玻璃对象创建透明填充材料。

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原文

From Wikipedia, the free encyclopedia

Chemical compound

Paraloid B-72 or B-72 is a thermoplastic resin that was created by Rohm and Haas for use as a surface coating and as a vehicle for flexographic ink. Subsequently, it has found popular use as an adhesive by conservator-restorers, specifically in the conservation and restoration of ceramic objects, glass objects,[1] the preparation of fossils, the hardening of piano hammers,[2][3] and can also be used for labeling museum objects.[4]

Paraloid B-72 in pellet form

B-72 is a durable and non-yellowing acrylic resin, which can be described chemically as an ethyl methacrylatemethyl acrylate copolymer. It is soluble in acetone, ethanol, toluene, and xylenes, among other solvents and solvent mixtures.[5]

One of the major advantages of B-72 as a consolidant is that it is stronger and harder than polyvinyl acetate without being extremely brittle. This adhesive is more flexible than many of the other typically used adhesives and tolerates more stress and strain on a join than most others. The major drawbacks to using B-72 are related to its handling properties: as in the case of other acrylic resins it is difficult to apply as an adhesive and to manipulate with precision.[6]

The most suitable solvent for B-72 is acetone. However, solvent mixtures with various proportions of acetone, ethanol, and toluene are frequently used to alter the working time of the resin and to produce slightly different properties (hardness and flexibility, e.g.) in the set resin. Unlike cellulose nitrate, B-72 does not need additives like plasticizers to stabilize its durability. Fumed colloidal silica can be added to help with the workability of the resin. Research shows that the silica better distributes the stress and strain that occurs during evaporation of a solvent and during the setting of the adhesive film.[6]: p.9 

Because of its transparency and versatility, conservators, led by Stephen Koob of the Corning Museum of Glass, have recently begun to use cast sheets of B-72 as a fill material in glass objects.[7]

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